Title
Copper Catalysis: Synthesis of Organosilicon Compounds: Catalytic Generation of CuSi Nucleophiles in Regioselective SN' Allylic,Used
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The present work is devoted to the catalytic generation of siliconbased cuprates and their application in several CSi bondforming reactions. A general procedure for the catalytic preparation of CuSi nucleophiles via activation of SiB interelement linkages is described. This versatile copper(I)catalyzed protocol involving formation of regioselective CSi bonds enables excess to a variety of organosilicon compounds. The detail investigations ascribing our preliminary attempts to transform into enantioselective variant in presence of different chiral ligands are also presented. In addition to this, the book also details on the study to explain the stereochemical surprises in reagent controlled Lewis acidmediated allylation of isatins with achiral allylic stannane.
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