CopperCatalyzed Electrophilic Amination of sp2 and sp3 CH Bonds (Springer Theses),Used

CopperCatalyzed Electrophilic Amination of sp2 and sp3 CH Bonds (Springer Theses),Used

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This thesis reports the latest developments in the direct amination of various CH bonds using an HZn exchange/electrophilic amination strategy. McDonald and coworkers reveal this approach to be a rapid and powerful method for accessing a variety of functionalized amines.The material outlined in this book shows how McDonald achieved CH zincation using strong, nonnucleophilic zinc bases and subsequent electrophilic amination of the corresponding zinc carbanions with copper as a catalyst and Obenzoylhydroxylamines as the electrophilic nitrogen source.McDonalds findings are of relevance to medicinal chemistry, drug discovery and materials science. Her thesis is a source of inspiration for scientists entering the field and students beginning their PhD in a related area.

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