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In dieser Arbeit wird die Entwicklung chiraler, katalytisch aktiver Polymere mit intrinsischer Mikroporositt vorgestellt. Verschiedene enantiomerenreine BINOLDerivate mit polymerisierbaren Substituenten wurden mittels der oxidativen Kupplung von Thiophenen polymerisiert. Die hergestellten Feststoffe wiesen intrinsische Mikroporositt und hohe spezifische Oberflchen von bis zu 1247 m2/g auf. Phosphorsurefunktionalisierte Monomere und Polymere konnten anschlieend erfolgreich als Organokatalysatoren in der enantioselektiven Transferhydrierung von Stickstoffheterocyclen eingesetzt werden. Die Polymerisation fhrte sowohl zur Immobilisierung als auch zur Verbesserung der Enantioselektivitt der monomeren Katalysatoren. Erste Untersuchungen zeigten, dass die heterogenen Katalysatoren einfach separiert und wiederverwendet werden knnen. Desweiteren wird ein polymerisierbarer OctahydroBINOLLigand vorgestellt, der den MonoalkoxyLiganden in den neusten SchrockMetatheseKatalysatoren nachempfunden ist und als Grundlage fr Untersuchungen zur Immobilisierung dieser Katalysatoren dienen kann.
⚠️ WARNING (California Proposition 65):
This product may contain chemicals known to the State of California to cause cancer,
birth defects, or other reproductive harm.
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