Equilibrium and Charge Transfer:: A study of the Iron(III) Nhydroxyethylethylenediammine N,NNtriacetic acid / Hexacyanoferrate,Used

Equilibrium and Charge Transfer:: A study of the Iron(III) Nhydroxyethylethylenediammine N,NNtriacetic acid / Hexacyanoferrate,Used

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SKU: DADAX3846500364
Brand: LAP Lambert Academic Publishing
Condition: New
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Cyanobridged mixed valence compounds have been known to exist since 1704, but a lot of interest in the binuclear and trinuclear species has emerged only more recently. The growing interest in these complexes is due mainly to their promising and useful applications in electrochromism, molecular magnetism and molecular electronics. These properties are activated by the excitation of their metaltometal charge transfer (MMCT) transition. This book characterizes aqueous solutions of the FeHEDTA / [Fe(CN)6]4 system which form intensely colored solutions that absorb strongly in the visible/NIR region of the electromagnetic spectrum. Typically binuclear (Fe(III)Fe(II)) and trinuclear (Fe(III)Fe(II)Fe(III)) complexes are formed. Information on reorganizational parameters, electronic coupling between metal centers, molar absorptivities, equilibrium constants, and delocalization factors are discussed for binuclear and trinuclear Fe(III)/Fe(II) complexes, and compared to similar systems reported in the literature. This book is ideal for researchers in chemistry, physics, material science, and engineering.

⚠️ WARNING (California Proposition 65):

This product may contain chemicals known to the State of California to cause cancer, birth defects, or other reproductive harm.

For more information, please visit www.P65Warnings.ca.gov.

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