Title
Material Designs and New Physical Properties in MX and MMXChain Compounds,Used
Delivery time: 8-12 business days (International)
This is the first book to comprehensively address the recent developments in both the experimental and theoretical aspects of quasionedimensional halogenbridged mono (MX) and binuclear metal (MMX) chain complexes of Pt, Pd and Ni. These complexes have onedimensional electronic structures, which cause the various physical properties as well as electronic structures. In most MXchain complexes, the Pt and Pd units are in M(II)M(IV) mixed valence or charge density wave (CDW) states due to electronphonon interactions, and Ni compounds are in Ni(III) averaged valence or MottHubbard states due to the onsite Coulomb repulsion. More recently, Pd(III) MottHubbard (MH) states have been realized in the ground state by using the chemical pressure. Pt and Pd chain complexes undergo photoinduced phase transitions from CDW to MH or metal states, and Ni chain complexes undergo photoinduced phase transitions from MH to metal states. Ni chain complexes with strong electron correlations show tremendous thirdorder optical nonlinearity and nonlinear electrical conductivities. They can be explained theoretically by using the extended PeierlsHubbard model. For MMXchain complexes, averaged valence, CDW, charge polarization, and alternating charge polarization states have been realized by using chemical modification and external stimuli, such as temperature, photoirradiation, pressure, and water vapor. All of the electronic structures and phase transitions can be explained theoretically.
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This warranty strictly does not cover damages that arose from negligence, misuse, wear and tear, or not in accordance with product instructions (dropping the product, etc.).
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