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This book addresses the coupling of a bimolecular transformation reaction with bounded rectilinear and spatially heterogeneous subsurface flows. It is shown that due to the action of local dispersion, at large time, the cross covariance budget is characterized by a balance between its rate of production and dissipation. This results in deriving a formula for effective reaction rate given by ?_eff??[1+2?D_ij ((?lnC_1)?(?x_i ))((?lnC_2)?(?x_j )) ] that accounts for the influence of concentration microstructure and smallscale mixing on the macroscopic bimolecular kinetics. For rectilinearly varying flows, a theoretical bound (using variational calculus) on dissipation time scale (?) is shown to be a tight bound. The formulation for reaction macrokinetics developed here provides a way to represent the influence of reactant concentration microstructure in largescale descriptions of reactive transport. The book should be useful to Theoretical Physicists, Theoretical Chemists, Mathematical Modelers, Computational (or Numerical) Modelers, Hydrogeologists, Turbulence enthusiasts, Civil, Chemical and Environmental Engineers.
⚠️ WARNING (California Proposition 65):
This product may contain chemicals known to the State of California to cause cancer,
birth defects, or other reproductive harm.
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