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Since nonclassical crystallization pathways were revealed, our picture of nucleation and crystal growth became in the last year quite confusing and ramified: we are confronted with the existence of liquid phases of amorphous calcium carbonate, polymerinduced liquid precursor and, last but not least, prenucleation clusters. This contribution explores: (a) The symmetrybreaking phaseselection of calcium carbonate, which is based upon a subtle interplay of interlinked equilibria and is ultimately ascribed to the weak parity violation energy difference. (b) A morphogenetic employment of mesocrystallinity: the intercrystalline minority constituent of a mesocrystal, e.g. occluded protein or polymeric additives, experiences compressionmolding which can be employed for the preparation of nanotubes of various materials, e.g. calcium carbonate or cadmium sulfide. (c) The existence of a liquid intermediate phase during metal carbonate formation. By a diffusioncontrolled and contractfree experimental setup, unequivocally evidence for the existence of nonclassical liquid intermediates, which precede the crystalline phase of bivalent carbonates at nearneutral conditions, is provided.
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