Novel Decavanadate Compounds for LithiumIon Batteries: En Route Towards a New Class of Highperformance Energy Materials (BestM,Used

Novel Decavanadate Compounds for LithiumIon Batteries: En Route Towards a New Class of Highperformance Energy Materials (BestM,Used

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Brand: Springer Spektrum
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Simon Greiner investigates the molecularlevel stabilization of polyoxovanadate (POV) compounds by rational design for the application as active cathode material in lithiumion batteries. Formation of a complex hydrogenbonding network locks the POVs in place and prevents thermal decomposition during electrode fabrication. The molecular vanadium oxide clusters can be electrochemically analyzed and show promising results for storage of multiple electrons per cluster, making these materials highly attractive for energy storage applications. Analytical methods comprise ATRFTIR, powder and singlecrystal XRD, electron microscopy, EDX, electrochemical analysis and battery testing.

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