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The general principles of polar rearrangements are brought together in this text, which deals with all the major rearrangements involving electrondeficient atoms or charged intermediates. Reactions involving migration to electrondeficient carbon, nitrogen, oxygen and sulphur, and sigmatropic rearrangements involving polar species, are thus treated in a coherent and consistent manner. Clear discussions of the reaction mechanisms are followed by examples of synthetic applications providing a concise yet comprehensive account of the nature of and importance of these processes.
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birth defects, or other reproductive harm.
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