Title
Teoriya YaMR khimicheskikh sdvigov ftora v aromaticheskikh molekulakh: Analiz i raschet khimicheskikh sdvigov (Russian Edition),Used
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Kniga sostoit iz dvukh chastey, pervaya iz kotorykh posvyashchena issledovaniyu vliyaniya vnutrimolekulyarnykh elektronnykh effektov na magnitnoe ekranirovanie yader ftora v aromaticheskikh molekulakh. Glavnoe vnimanie udeleno vyyasneniyu prirody anomal'nykh variatsiy khimicheskikh sdvigov ftora v orto i polizameshchennykh ftorbenzolakh. Razrabotannaya poluempiricheskaya skhema khimicheskikh sdvigov pozvolila predstavit' ikh v vide additivnoy summy vnutrimolekulyarnykh elektronnykh effektov. Predlagaemaya model' pozvolila kolichestvenno opisat' dostatochno raznoobraznyy eksperimental'nyy material. Vo vtoroy chasti uchityvaetsya vliyanie mezhmolekulyarnykh vzaimodeystviy na variatsii khimicheskogo sdviga v razlichnykh kondensirovannykh sredakh: aprotonnykh i protonnykh rastvoritelyakh, nepolyarnykh i polyarnykh. Analiziruetsya vliyanie na ekranirovanie lineynogo i kvadratichnogo vneshnego elektricheskogo polya, vandervaal'sovskikh vzaimodeystviy, a dlya polyarnykh molekul, v ramkakh kontinual'noy dielektricheskoy modeli, uchityvaetsya takzhe vliyanie polya reaktsii. V ramkakh predlagaemoy modeli ob"yasnena temperaturnaya zavisimost' khimicheskogo sdviga. Issledovaniya, predstavlennye v etoy monografii v osnovnom opirayutsya na rezul'taty rabot, vypolnennykh avtorom.
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