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Help
If you have any questions, you are always welcome to contact us. We'll get back to you as soon as possible, withing 24 hours on weekdays.
Customer service
All questions about your order, return and delivery must be sent to our customer service team by e-mail at yourstore@yourdomain.com
Sale & Press
If you are interested in selling our products, need more information about our brand or wish to make a collaboration, please contact us at press@yourdomain.com
Kniga sostoit iz dvukh chastey, pervaya iz kotorykh posvyashchena issledovaniyu vliyaniya vnutrimolekulyarnykh elektronnykh effektov na magnitnoe ekranirovanie yader ftora v aromaticheskikh molekulakh. Glavnoe vnimanie udeleno vyyasneniyu prirody anomal'nykh variatsiy khimicheskikh sdvigov ftora v orto i polizameshchennykh ftorbenzolakh. Razrabotannaya poluempiricheskaya skhema khimicheskikh sdvigov pozvolila predstavit' ikh v vide additivnoy summy vnutrimolekulyarnykh elektronnykh effektov. Predlagaemaya model' pozvolila kolichestvenno opisat' dostatochno raznoobraznyy eksperimental'nyy material. Vo vtoroy chasti uchityvaetsya vliyanie mezhmolekulyarnykh vzaimodeystviy na variatsii khimicheskogo sdviga v razlichnykh kondensirovannykh sredakh: aprotonnykh i protonnykh rastvoritelyakh, nepolyarnykh i polyarnykh. Analiziruetsya vliyanie na ekranirovanie lineynogo i kvadratichnogo vneshnego elektricheskogo polya, vandervaal'sovskikh vzaimodeystviy, a dlya polyarnykh molekul, v ramkakh kontinual'noy dielektricheskoy modeli, uchityvaetsya takzhe vliyanie polya reaktsii. V ramkakh predlagaemoy modeli ob"yasnena temperaturnaya zavisimost' khimicheskogo sdviga. Issledovaniya, predstavlennye v etoy monografii v osnovnom opirayutsya na rezul'taty rabot, vypolnennykh avtorom.
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