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The Barbier Reaction and Related OneStep Processes (Reactivity and Structure: Concepts in Organic Chemistry, 31),Used
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The significant increase in applications of Barbier and Barbiertype reactions in (in) organic synthesis over the past twentyfive years, combined with repeated stimulation on the part of SpringerVerlag (Dr. R. Stumpe) were strong in centives for me to write this book. My earliest activities in this field include a modest and firstever review article (in cooperation with Dr. F. A. Hartog who at that time (1977) did his doctoral research on the Barbier reaction). References to this review article, as mentioned in the Science Citation Index till recently are a good indication for a continued interest in this simple synthetic procedure. The subtitle of this monograph, Related OneStep Processes, may require the following clarification. A synthesis with the aid of an organometallic compound is usually carried out in two steps: 1) the organometallic reagent is prepared from an organo halide and a metal in a solvent, 2) a chosen substrate is added to this reagent. In a Barbier reaction these two steps are combined: a mixture of the organo halide and the substrate is added to a suspension of the metalin an appropriate solvent.
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