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The principal idea of this volume is to offer a Capita Selecta of unconventional and thoughtprovoking topics in organometallic chemistry, presented by experts in each field. As intended, this approach leads either to reviews covering a specific uncommon class of organometallic compounds or to overviews which relate uncommon physical properties with various classes of organometallic compounds. The contributions are streamlined thus onto two main axes unusual properties reflecting structures and bonding situations, on the one hand, and uncommon structural features or structurereactivity relationships, on the other. Extensive crossreferencing of useful information is provided, making this volume accessible for people working in rather different areas of organometallic chemistry.The synthesis of molecules with 'extreme' properties is a challenge for all those working in organometallic chemistry, irrelevant of theoretical/computational, synthetic or application interests. This book presents case studies at the interface of these overlapping interests.Unusual Structures and Physical Properties in Organometallic Chemistry:* Provides test cases for computational and theoretical models* Presents a challenge for synthetic chemists* Provides ideal show cases for analytical techniquesThis volume will be an invaluable reference for researchers in organometallic chemistry, computational and theoretical chemistry, NMR and other spectroscopic methods.
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