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gem.Digalogentsiklopropany legko obrazuyutsya v rezul'tate [2+1]prisoedineniya digalogenkarbenov po kratnym ugleroduglerodnym svyazyam. Eti soedineniya predstavlyayut znachitel'nyy interes kak poluprodukty i reagenty v sinteze biologicheski aktivnykh preparatov. Kniga posvyashchena sovremennym problemam polucheniya i transformatsii gem.digalogentsiklopropanov razlichnogo stroeniya. V ney rassmotreny osnovnye puti obrazovaniya gem.digalogentsiklopropanovykh struktur; rassmotreno vliyanie stroeniya nepredel'nykh soedineniy i karbenov na regio i stereoselektivnost' [2+1]prisoedineniya. Pokazano, chto digalogenkarbeny sposobny vnedryat'sya po slabym uglerodvodorodnym svyazyam, smezhnym s geteroatomami. Rassmotreny reaktsii gem.digalogentsiklopropanov (O, N, Calkilirovanie, gomo i sopolimerizatsiya, vosstanovlenie i okislenie), protekayushchie s zameshcheniem galogenov, libo s rasshchepleniem karbotsikla. Pri etom, okazyvaetsya vozmozhnym kak poluchenie polizameshchennykh tsiklicheskikh soedineniy, tak i obrazovanie atsiklicheskikh alkenov i alkinov, soderzhashchie geteroatomy. Kniga prednaznachena dlya studentov, aspirantov, prepodavateley, a takzhe dlya shirokogo kruga khimikovorganikov, rabotayushchikh v oblasti organicheskogo kataliza.
⚠️ WARNING (California Proposition 65):
This product may contain chemicals known to the State of California to cause cancer,
birth defects, or other reproductive harm.
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