Title
Volume Holographic Recording Utilizing PhotoInitiated Polymerization: Volume Holographic Recording Utilizing PhotoInitiated Po,Used
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This monogram evaluates the important physical properties of volume holographic recording in sufficiently thick photopolymer materials that have provided a promising alternative for nonvolatile (WORM) systems. Unlike prior studies that had focused on diffusion limited volume grating formation during illumination, ignoring any postexposure grating development, this work investigated the complete dynamics of volume holographic recording including postexposure grating development . In a material utilizing cationingringopening polymerization, the significant postexposure grating development observed at high I recordings, was identified to allow eventually for strong final gratings (35 cm/mJ) without diffusion limitations. Based on these observations, a comprehensive new physical model was developed to describe holographic recording utilizing photoinitiated, rather than photoinduced, polymerization, which accounted accurately for the physical recording properties that allow for efficient nonvolatile holographic digital storage in these photopolymer media.
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